In any gamma-spectrometric measurement with semiconductor detectors, the task of **converting the number of counts** – collected by a multichannel analyzer (MCA) in a full gamma-energy peak – **into the activity of the sample/source** cannot be avoided. There are, in principle, three approaches to this issue: relative, absolute and semi-empirical.

The relative method is more accurate, but less flexible to changing experimental conditions, while absolute ones (e.g. Monte Carlo) are beautifully exact and flexible, but often too demanding where the extent and accuracy of the required input data are concerned.

**The semi-empirical approach** takes advantage of the positive attributes of both the relative and absolute methodologies, simultaneously minimizing their drawbacks. This brings us to the determination of full-energy peak efficiency (ε_{p}), an energy dependent characteristic of the detector for a given counting arrangement. Semi-empirical methods commonly consist of two parts: experimental (producing reference efficiency characteristic of the detector) and relative-to-this accuracy in the calculation of ε_{p}. The inherent inflexibility of the relative method is avoided in this way, as well as the demand for the many physical parameters needed in absolute calculations.

Numerous variations exist within the semi-empirical approach, with regard to either the experimental or to the computational elements. It is important to note that only the simultaneous differential treatment of

- gamma-attenuation,
- counting geometry and
- detector response

can be justified. Attempting to separately calculate these three physical phenomena, generally leads to (over)simplifications, which further require complex corrections with the chance of only limited success.

This fact is transformed into the concept of the **effective solid angle** (Ω) – a calculated value incorporating the three components, and closely related to the detection efficiency. This assumes that the virtual peak-to-total ratio is in fact an intrinsic characteristic of the detector crystal (depending on gamma energy only), and leads to ε_{p} being proportional to Ω. The detection efficiency is then found as:

ε_{p} = ε_{p,ref} (Ω/Ω_{ref})

which is the basis of the **“efficiency transfer” principle**. Efficiency transfer factor (ET) is thus the ratio of the actual to reference efficiency at a given gamma-energy.

The ET approach is extremely useful, offering:

- practically unlimited flexibility in sample type and size, matrix composition, detector choice and source detector counting arrangement and
- cancelling out much of the impact of input data uncertainties (especially those of the detector) on final ε
_{p}calculation result.

This implicit latter “ET error-compensation” lends to ET an important advantage over purely mathematical (Monte Carlo) efficiency calculation approaches.

Therefore, in order to apply this method the following should be known:

**reference efficiency curve**, usually obtained by counting calibrated source(s) at reference geometry(ies) and covering gamma-energies in the region of interest; some effort should be put in into this phase to reach an accurate ε_{p}vs. E_{γ}function, as this fully pays off in further exploitation;**geometrical and compositional data**about the source, detector, and all absorbing layers (source container and holder, detector end-cap and housing, dead layers, etc.) and**gamma-attenuation coefficients**for all materials involved (normally a data file in the computer program).

**Angle software** is a computer program which performs these calculations. In its various forms, Angle has been in use for more than 20 years now in numerous gamma-spectrometry based analytical laboratories worldwide.

The program can be applied to practically all situations encountered in gamma-laboratory practice: point, disc, cylindrical or Marinelli samples, small and large, of any matrix composition. No standards are required, but a start-up “**reference efficiency curve**” (**REC**) should be obtained (“once for ever”) by measuring a calibrated source at some reference counting geometry. Calibration sources should cover gamma-energy region of analytical interest (e.g. 50-3000keV). It is suggested that calibrated sources with low certified uncertainties (not exceeding 1.5%-2.5%) are used to obtain as many calibration points (efficiencies vs. gamma-energies) as possible for the energy range mentioned. This non-negligible initial effort is largely paid back in future exploitation, since an accurate reference efficiency curve is the basis for the accurate application of Angle.

One REC per detector is enough, in principle. It is recommended to construct it by counting a number of calibrated point sources at a large distance from the detector (e.g. 20-30 cm), avoiding true coincidences and matrix effects. Also, absolutely calibrated point sources are often certified to better accuracy than voluminous ones. It is generally more prudent to use several single-nuclide sources, than a single multi-nuclide one.

However, in order to additionally exploit the ET error-compensation effect, one might consider constructing more RECs for the same detector. For instance, the same point source(s) counted at a large distance could also be counted on the detector top, yielding another REC. Calibrated cylindrical and Marinelli sources could also produce additional RECs.

In an ideal case, using any of several RECs in ε_{p} calculations would produce the same result for the actual sample, i.e. the result should be independent of the choice of the REC. Given the fact that all input data (detector, source, geometry, etc.) are inaccurate to some extent, choosing a “**likely**” **REC** for the actual sample/geometry should eventually produce better (more accurate) results, due to a larger ET error-compensation. In other words, if the REC sample/geometry is closer to the actual sample, the results are likely to be better. This in itself is a measure of the accuracy of the various sample and detector parameter choices – if two RECs produce results which are close, the implication is that both sample/geometry and detector are well characterized.

Angle allows multiple RECs to be employed for a given detector, so that varying the REC can be one of the elements in the optimization of gamma-spectrometry analytical procedure.

In short, Angle software is characterized by:

- broad application range, covering the vast majority of situations encountered in gamma-spectrometry practice;
- high accuracy (uncertainties of calculated detector efficiencies are of the order of a few percent – usually less than that for other sources of uncertainty in the measurement), based upon the concept of the ET and effective solid angle calculations;
- easy data manipulation with a friendly and intuitive graphical user interface;
- short computation times of the order of seconds on standard PCs (normally not more than a minute even for the most complex calculations);
- flexibility with respect to changing input parameters, which enables easy estimation of the impact of a particular parameter on the detection efficiency and, related to this
- teaching/training aspect (for example, in gamma-spectrometry courses), since practically all parameters characterizing the detection process are found therein, systematically grouped and easy to follow and understand;
- no need for any “factory characterization” of the detector – Angle can be used with any HPGE detector; when necessary, the detector performance is easily re-validated without intervention from the vendor;
- possibility to expand, so as to meet changing users’ counting conditions/requirements ;
- the opportunity to accommodate other ET methods for efficiency calculations2.

Given a gamma-source (*S*) and a detector (*D*), the effective solid angle is defined as:

(1)

with *V _{S}* = source volume,

(2)

Here *T* is a point varying over *V _{S}*,

With ε_{p} being proportional to Ω, the detection efficiency is found as:

(3)

where index “ref” denotes reference counting geometry to which the actual one is relative.

So as to apply this method the following should be known:

- reference efficiency curve, usually obtained by counting calibrated source(s) at a reference geometry and covering gamma-energies (E
_{γ}) in the region of interest (e.g. 50–3000 keV); considerable effort should be put into this phase to reach an accurate ε_{p}vs. E_{γ}function, but it fully pays off in further exploitation; - geometrical and compositional data about the source, detector and all absorbing layers (source container and holder, detector end-cap and housing, dead layers, etc.);
- gamma-attenuation coefficients for all materials involved.

For a cylindrical source coaxially positioned with the detector, and with a radius smaller than that of the detector (*r*_{0} < *R*_{0}). Eq. (1) then gives

(4)

In the above, a fivefold integral is reduced to fourfold due to axial symmetry. Disk and point sources are included in Eq. (4) (for *L* = 0, and *L* = 0, *r*_{0} = 0, respectively).

For sources with radii larger than that of the detector (*r*_{0} > *R*_{0}) we have:

(5)

with

Marinelli geometry can be described by:

(6)

When treating well detectors we obtain:

(7)

In this case, points *T* and *P* have the following coordinates, respectively for the three terms:

The above described effective solid angles and corresponding detector efficiencies represent the theoretical basis for Angle software calculations. These account for the majority of counting situations in γ-spectrometry practice.